1 to 3 of 3 Results
Feb 7, 2022
Panyam, Pradeep Kumar Reddy; Atwi, Boshra; Ziegler, Felix; Frey, Wolfgang; Nowakowski, Michal; Bauer, Matthias; Buchmeiser, Michael, 2022, "Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes", https://doi.org/10.18419/darus-2473, DaRUS, V1
Novel Rh(III) pentamethylcyclopentadienyl and Rh(I) complexes containing chelating N-heterocyclic carbenes have been prepared and used in the hydrosilylation of 1-alkynes. Selected catalysts were immobilized within the mesopores of SBA-15. The confinement effects either provided... |
Apr 22, 2021
Panyam, Pradeep Kumar Reddy; Stöhr, Laura; Wang, Dongren; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Chromium(VI) Bisimido Dichloro, Bisimido Alkylidene, and Chromium(V) Bisimido Iodo N‐Heterocyclic Carbene Complexes", https://doi.org/10.18419/darus-1686, DaRUS, V1
Reaction of CrCl2(N-tBu)2 with 1,3-dimethylimidazol-2-ylidene (IMe), 1,3-dimethyl-4,5-dichloroimidazol-2-ylidene (IMeCl2), 1,3-di(2-propyl)imidazol-2-ylidene (IPr), 1,3-dimesitylimidazol-2-ylidene (IMes) and 1,3-bis(2,6-(2-Pr)2C6H3)imidazol-2-ylidene (IDipp) yields the correspond... |
Mar 19, 2021
Musso, Janis; Benedikter, Mathis; Gebel, Paul; Elser, Iris; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication Data for: Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route", https://doi.org/10.18419/darus-1670, DaRUS, V1
A general route to tungsten(VI) imido alkylidene bispyrrolide complexes via the extrusion of CO2 from the reaction of one equivalent of an aryl isocyanate with WOCl4 to form the corresponding imido complexes is reported. The Dataset contains the NMR spectra of figures S1 and S2 (... |