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1 to 10 of 10 Results
Apr 9, 2021
Elser, Iris; Groos, Jonas; Hauser, Philipp Manuel; van der Ende, Melita; Koy, Maximilian, 2021, "Publication data for: "Molybdenum and Tungsten Alkylidyne Complexes Containing Mono-, Bi-, and Tridentate N-Heterocyclic Carbenes" - data from Buchmeiser group", https://doi.org/10.18419/darus-1689, DaRUS, V1
All primary data files and processed data of the journal article from Buchmeiser group. NMR data is in the folder NMR divided in NMR experiments and pure compounds which consists of the NMR spectra of pure compounds.The TONs in table 2 were determined by GC-MS. GC-MS data is in t...
Apr 9, 2021
Schowner, Roman; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes", https://doi.org/10.18419/darus-1705, DaRUS, V1
Data on novel synthetic approaches to molybdenum imido alkylidene N‐heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl‐substituted imido ligands, highly basic 6‐Mes (6‐Mes = 1,3‐dimesityl‐3,4,5,6‐tetrahydropyrimidin‐2‐yli...
Apr 8, 2021
Musso, Janis; Benedikter, Mathis; Wang, Dongren; Frey, Wolfgang; Altmann, Hagen J.; Buchmeiser, Michael, 2021, "Data of: Reversible N‐Heterocyclic Carbene‐Induced α‐H Abstraction in Tungsten(VI) Imido Dialkyl Dialkoxide Complexes", https://doi.org/10.18419/darus-1715, DaRUS, V1
The first reversible N‐heterocyclic carbene (NHC) induced α‐H abstraction in tungsten(VI) imido‐dialkyl dialkoxide complexes is reported. Treatment of W(NAr)(CH2Ph)2(OtBu)2 (Ar=2,6‐dichlorophenyl, 2,6‐dimethylphenyl, 2,6‐diisopropylphenyl) with different NHCs leads to the formati...
Apr 6, 2021
Momin, Mohasin, 2021, "Data for: Stereoselective Olefin Ring-Opening Cross Metathesis Catalyzed by Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes", https://doi.org/10.18419/darus-1694, DaRUS, V1
The influence of the structure of cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) catalysts, i. e. of [Mo(N-2-tert-butyl-C6H4) (CHCMe2Ph)(NHC)X+ B(ArF)4 ] (NHC=1,3-di(2-Pr) imidazol-2-ylidene (iPr), 1,3-dimesitylimidazol-2-ylidene (IMes); X=pyrrolide, OCH(CF3)2,...
Apr 6, 2021
Momin, Mohasin; Musso, Janis; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Data for: Tuning the Latent Behavior of Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes in Dicyclopentadiene Polymerization", https://doi.org/10.18419/darus-1696, DaRUS, V1
We report the synthesis of O- and N-chelated hexacoordinated molybdenum imido alkylidene N-heterocyclic carbene (NHC) bistriflate and pentacoordinated molybdenum imido alkylidene NHC monotriflate monoalkoxide complexes and their use as thermally latent and in some cases air-stabl...
Mar 26, 2021
Hauser, Philipp Manuel; van der Ende, Melita; Groos, Jonas; Frey, Wolfgang; Wang, Dongren; Buchmeiser, Michael, 2021, "Data for "Cationic Tungsten Alkylidyne N‐Heterocyclic Carbene Complexes: Synthesis and Reactivity in Alkyne Metathesis"", https://doi.org/10.18419/darus-1679, DaRUS, V1
All primary data files and processed data of the journal article from Buchmeiser group. Productivities in alkyne metathesis reactions (Paper, Table 1) was examined via gas-chromatography / mass spectrometry analysis and can be found in the GC-MS data folder. Novel complexes were...
Mar 25, 2021
Kesharwani, Manoj Kumar; Elser, Iris; Musso, Janis; Buchmeiser, Michael; Kästner, Johannes, 2021, "Replication data of Buchmeiser group for: Reaction Mechanism of Ring-Closing Metathesis with a Cationic Molybdenum Imido Alkylidene N‑Heterocyclic Carbene Catalyst", https://doi.org/10.18419/darus-1714, DaRUS, V1
DFT calculations were carried out to explore all relevant pathways for the ring-closing metathesis (RCM) reaction of a cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) catalyst with α,ω-dienes.The 1H NMR spectrum of the reaction between [Mo(N-2,6-Me2-C6H3)(CHCMe2...
Mar 23, 2021
Hauser, Philipp Manuel; Musso, Janis; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Publication data for: "Cationic Tungsten Oxo Alkylidene N-Heterocyclic Carbene Complexes via Hydrolysis of Cationic Alkylidyne Progenitors"", https://doi.org/10.18419/darus-1772, DaRUS, V1
All primary data files and processed data of the journal article from Buchmeiser group, in which cationic tungsten oxo NHC complexes are synthesized via hydrolysis of cationic alkylidyne NHC complexes. NMR data of all pure compounds and NMR experiments. Gc-MS data of Metathesis r...
Mar 19, 2021
Musso, Janis; Benedikter, Mathis; Gebel, Paul; Elser, Iris; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication Data for: Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route", https://doi.org/10.18419/darus-1670, DaRUS, V1
A general route to tungsten(VI) imido alkylidene bispyrrolide complexes via the extrusion of CO2 from the reaction of one equivalent of an aryl isocyanate with WOCl4 to form the corresponding imido complexes is reported. The Dataset contains the NMR spectra of figures S1 and S2 (...
Dec 23, 2020
Ziegler, Felix, 2020, "Olefin Metathesis in Confined Geometries: A Biomimetic Approach toward Selective Macrocyclization Data Buchmeiser", https://doi.org/10.18419/darus-832, DaRUS, V1
This paper addresses the synthesis of macrocyclic molecules by a spatial confinement effect in SBA-15. Various aspects such as concentration dependence, substrate size and temperature dependence have been discussed. In the attached data you will find all NMR spectra of the perfor...
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