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Data for "Lewis Pair Polymerization of Epoxides via Zwitterionic Species as a Route to High‐Molar‐Mass Polyethers"
Jul 27, 2023
Walther, Patrick; Krauß, Annabelle; Naumann, Stefan, 2023, "Data for "Lewis Pair Polymerization of Epoxides via Zwitterionic Species as a Route to High‐Molar‐Mass Polyethers"", https://doi.org/10.18419/darus-1817, DaRUS, V1
A dual catalytic setup based on N‐heterocyclic olefins (NHOs) and magnesium bis(hexamethyldisilazide) (Mg(HMDS)2) was used to prepare poly(propylene oxide) with a molar mass (Mn) >500 000 g mol-1, in some cases even >106 g mol-1, as determined by GPC/light scattering. This is ach...
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