SFB 1333 A5 - Bill group, IMW

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Figure 2 Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers JPEG Image - 69.8 KB - MD5: d1ce2cd264a1722749cca57f3b80c4d5 Scanning electron microscope (SEM) a) cross‐section and b) top‐view images of a polycrystalline ZnO film deposited on a Si/Cr/Au substrate via CBD.
Figure 3 Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers JPEG Image - 46.9 KB - MD5: 39b455a2eb1298aba2c69f40c45513a5 PM‐IRRAS absorbance spectra of a) bare polycrystalline ZnO, b) AzPT, and c) AzPTES immobilized on polycrystalline ZnO (the structures of AzPT and AzPTES are shown as insets in (b) and (c)). The corresponding vibrational labels are included for reference.
Figure 4 Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers JPEG Image - 169.0 KB - MD5: a3f16b97937adcb2a0377f3a75645c81 XPS spectra of AzPT immobilized on polycrystalline ZnO. The resolved a) Zn 2p3/2, b) O 1s, c) C 1s, d) N 1s, and e) S 2p peaks are shown.
Figure 5 Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers JPEG Image - 153.0 KB - MD5: 401da94c790276ed8a9da74a3c265c73 XPS spectra of AzPTES immobilized on polycrystalline ZnO. The resolved a) Zn 2p3/2, b) O 1s, c) C1s, d) N 1s, and e) Si 2p peaks are shown.
Figure 9 Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers JPEG Image - 243.5 KB - MD5: 41498ec9a50f193443ae5f15cec9e1f3 XPS a) S2p and b) Si 2p spectra for AzPT and AzPTES SAMs immobilized on (0001)‐O, (0001)‐Zn, and (1010) ZnO surfaces.
Figure S10.tif Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers TIFF Image - 1.8 MB - MD5: e7f7708e7537597581b7c378375a07b6 XPS spectra of the chiral diene ligand immobilized on AzPTES functionalized polycrystalline ZnO via azide-alkyne cycloaddition. The resolved a) Zn 2p3/2, b) O 1s, c) C 1s, d) N 1s and e) Si 2p species are shown.
Figure S11.tif Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers TIFF Image - 478.3 KB - MD5: c24215b023c236ec09e071319f53f612 XPS spectra of the molecular Rh catalyst complexed with the chiral diene ligand immobilized on AzPTES functionalized polycrystalline ZnO via azide-alkyne cycloaddition. The resolved a) Zn 2p3/2, b) O 1s, c) N 1s, d) Si 2p and e) Rh 3d peaks are shown.
Figure S1.tif Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers TIFF Image - 1.5 MB - MD5: f9970810db3ca531d5bca8aa811c4249 AFM a) height and b) amplitude images of a polycrystalline ZnO film fabricated via CBD.
Figure S2.tif Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers TIFF Image - 658.1 KB - MD5: 3f2f7767546efbbf88afbce3054a5e64 XPS spectra of AzPT immobilized on (0001)-O ZnO. The resolved a) Zn 2p3/2, b) O 1s c) C 1s, d) N 1s and e) S 2p peaks are shown.
Figure S3.tif Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers TIFF Image - 1.7 MB - MD5: 6ce7411b0c401f2e68d3087a4704a725 XPS spectra of AzPTES immobilized on (0001)-O ZnO. The resolved a) Zn 2p3/2, b) O 1s, c) C 1s, d) N 1s and e) Si 2p peaks are shown.

Figure 2

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

JPEG Image - 69.8 KB -

Scanning electron microscope (SEM) a) cross‐section and b) top‐view images of a polycrystalline ZnO film deposited on a Si/Cr/Au substrate via CBD.

Figure 3

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

JPEG Image - 46.9 KB -

PM‐IRRAS absorbance spectra of a) bare polycrystalline ZnO, b) AzPT, and c) AzPTES immobilized on polycrystalline ZnO (the structures of AzPT and AzPTES are shown as insets in (b) and (c)). The corresponding vibrational labels are included for reference.

Figure 4

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

JPEG Image - 169.0 KB -

XPS spectra of AzPT immobilized on polycrystalline ZnO. The resolved a) Zn 2p3/2, b) O 1s, c) C 1s, d) N 1s, and e) S 2p peaks are shown.

Figure 5

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

JPEG Image - 153.0 KB -

XPS spectra of AzPTES immobilized on polycrystalline ZnO. The resolved a) Zn 2p3/2, b) O 1s, c) C1s, d) N 1s, and e) Si 2p peaks are shown.

Figure 9

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

JPEG Image - 243.5 KB -

XPS a) S2p and b) Si 2p spectra for AzPT and AzPTES SAMs immobilized on (0001)‐O, (0001)‐Zn, and (1010) ZnO surfaces.

Figure S10.tif

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

TIFF Image - 1.8 MB -

XPS spectra of the chiral diene ligand immobilized on AzPTES functionalized polycrystalline ZnO via azide-alkyne cycloaddition. The resolved a) Zn 2p3/2, b) O 1s, c) C 1s, d) N 1s and e) Si 2p species are shown.

Figure S11.tif

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

TIFF Image - 478.3 KB -

XPS spectra of the molecular Rh catalyst complexed with the chiral diene ligand immobilized on AzPTES functionalized polycrystalline ZnO via azide-alkyne cycloaddition. The resolved a) Zn 2p3/2, b) O 1s, c) N 1s, d) Si 2p and e) Rh 3d peaks are shown.

Figure S1.tif

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

TIFF Image - 1.5 MB -

AFM a) height and b) amplitude images of a polycrystalline ZnO film fabricated via CBD.

Figure S2.tif

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

TIFF Image - 658.1 KB -

XPS spectra of AzPT immobilized on (0001)-O ZnO. The resolved a) Zn 2p3/2, b) O 1s c) C 1s, d) N 1s and e) S 2p peaks are shown.

Figure S3.tif

Apr 9, 2024 - Replication Data for: A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

TIFF Image - 1.7 MB -

XPS spectra of AzPTES immobilized on (0001)-O ZnO. The resolved a) Zn 2p3/2, b) O 1s, c) C 1s, d) N 1s and e) Si 2p peaks are shown.

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