Replication Data for: "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement"

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Beurer, Ann-Katrin; Kirchhof, Manuel; Bruckner, Johanna R.; Dyballa, Michael, 2021, "Replication Data for: "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement"", https://doi.org/10.18419/darus-1774, DaRUS, V1
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Subtitle Data of all participating research groups
Description
The manuscript describes a method, which ensures a selective functionalization of the mesopore surface with a clickable linker and thus makes it possible to study confinement effects during catalyzed reactions. First, the silanol groups on the particle surface and in the pore entrances of the SBA-15 are passivated. By solvent extraction, the template is removed and afterwards the pore walls are functionalized with 3-azidopropyltriethoxysilane before the catalyst is clicked on the pore walls. In initial experiments of asymmetric Rh-catalyzed 1,2-addition, the performance of a catalyst clicked selectively on the mesopore walls is investigated. The data used for the manuscript are sorted by the respective characterization method.The data are named either according to the sample name, the entry or the figure in the paper. All data are raw data that can be processed with the corresponding software.
Subject Chemistry
Keyword spatially controlled functionalization, asymmetric catalysis, confinement
Related Publication A.-K. Beurer, M. Kirchhof, J. R. Bruckner, W. Frey, A. Baro, M. Dyballa, F. Giesselmann, Y. Traa (2021), "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement", ChemCatChem doi: 10.1002/cctc.202100229
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Masse von Supernatant - Ligandenstabilität.zip
ZIP Archive - 36.3 KB
Published May 5, 2021
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MD5: 3852f435ab81e0f6edea9240ea75e954
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Röntgen-Daten_Verbindungen.zip
ZIP Archive - 500.0 KB
Published May 5, 2021
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MD5: ec7998335e10db84a2fb039ffd6019d8
X-ray of the linkers
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Background.zip
13C MAS NMR/ZIP Archive - 289.0 KB
Published May 5, 2021
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MD5: 7c26100adceef0119803f1561a9dc43f
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Figure 3a.zip
13C MAS NMR/ZIP Archive - 74.6 KB
Published May 5, 2021
29 Downloads
MD5: 0ad479f13da719daa3676e3660dbcf54
SBA-15-ex-E-p-in6
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Figure 4a 3b.zip
13C MAS NMR/ZIP Archive - 72.3 KB
Published May 5, 2021
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MD5: 9ba849350be2c84da0b8a1dba22f5256
SBA-15-ex+in
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Figure 4b.zip
13C MAS NMR/ZIP Archive - 73.6 KB
Published May 5, 2021
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MD5: 1f23d2f133b9d8bce3395b75344a6654
SBA-15-ex+in-2a
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DTA_SBA-15-as-synthesized.txt
DTA/Plain Text - 397.0 KB
Published May 5, 2021
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MD5: 98bdc87872a452c87d4e55ebccad8c74
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DTA_SBA-15-calcined_air.txt
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Published May 5, 2021
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MD5: 8dbcca6b656e0d786dbe454f8b33411b
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DTA_SBA-15-calcined_N2.txt
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Published May 5, 2021
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MD5: ee040daaaec0d5d570ea81844dbb4055
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DTA_SBA-15-ex+in-HMDS_air.txt
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Published May 5, 2021
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MD5: 5eab249cb3aa24c6690caa7cc965e1ea
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