Replication data of Lotsch group for: "Postsynthetic Transformation of Imine- into Nitrone-Linked Covalent Organic Frameworks for Atmospheric Water Harvesting at Decreased Humidity"

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Grunenberg, Lars; Savasci, Gökcen; Emmerling, Sebastian; Heck, Fabian; Bette, Sebastian; Cima Bergesch, Afonso; Ochsenfeld, Christian; Lotsch, Bettina V., 2024, "Replication data of Lotsch group for: "Postsynthetic Transformation of Imine- into Nitrone-Linked Covalent Organic Frameworks for Atmospheric Water Harvesting at Decreased Humidity"", https://doi.org/10.18419/DARUS-3658, DaRUS, V1, UNF:6:6qLrfVdxi4dySJ6NPLMHUw== [fileUNF]
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Description
Herein, we report a facile postsynthetic linkage conversion method giving synthetic access to nitrone-linked covalent organic frameworks (COFs) from imine- and amine-linked COFs. The new two-dimensional (2D) nitrone-linked covalent organic frameworks, NO-PI-3-COF and NO-TTI-COF, are obtained with high crystallinity and large surface areas. Nitrone-modified pore channels induce condensation of water vapor at 20% lower humidity compared to their amine- or imine-linked precursor COFs. Thus, the topochemical transformation to nitrone linkages constitutes an attractive approach to postsynthetically fine-tune water adsorption properties in framework materials. Open *.cif files with a visualization software (see http://ww1.iucr.org/iucr-top/cif/), *.raw files with WinXPOW, *.txt, *.csv, *.xyd and *.aif files with a text editor, *.sp files with PerkinElmer Spectrum software, *.mnova files with MestReNova, and *.pro files with TOPAS.
Subject Chemistry
Keyword Adsorption, Covalent Organic Frameworks, Materials, Nitrogen Compounds, Oxidation
Related Publication L. Grunenberg, G. Savasci, S.T. Emmerling, F. Heck, S. Bette, A. Cima Bergesch, C. Ochsenfeld and B.V. Lotsch J. Am. Chem. Soc. 2023, 145, 24, 13241-13248.doi: 10.1021/jacs.3c02572
Notes View data by "tree" to understand the file structure and file names according to the designations used in the original publication.
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LG-325.sp
DaRUS/FT-IR/NO-PI-3-COF/Unknown - 30.3 KB
Published Jan 29, 2024
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MD5: f1a0fe4ab14a1790492c948af9d2aaaf
LG-325.tab
DaRUS/FT-IR/NO-PI-3-COF/Tabular Data - 54.5 KB
Published Jan 29, 2024
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3 Variables, 3552 Observations UNF:6:BDQiw4MF2sNCy3Vq98yt0Q==
LG-325dryS.csv
DaRUS/FT-IR/NO-PI-3-COF/Comma Separated Values - 51.6 KB
Published Jan 29, 2024
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MD5: 2ba365d4e153dd49e4c8203d469dfac9
LG-325dryS.sp
DaRUS/FT-IR/NO-PI-3-COF/Unknown - 30.3 KB
Published Jan 29, 2024
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MD5: 4eda99e821e50be0987eb9e0bd1faf7d
LG-387-333_Dioxan.csv
DaRUS/FT-IR/NO-PI-3-COF/solvent stability/Comma Separated Values - 51.9 KB
Published Jan 29, 2024
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MD5: e2d6042605e8fdf2ce339530c0f8b530
LG-387-333_Dioxan.sp
DaRUS/FT-IR/NO-PI-3-COF/solvent stability/Unknown - 30.4 KB
Published Jan 29, 2024
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MD5: 268c4121035599e5285523c954edd14e
LG-387_333_Aceton-bgnew.csv
DaRUS/FT-IR/NO-PI-3-COF/solvent stability/Comma Separated Values - 51.6 KB
Published Jan 29, 2024
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MD5: 966e468567f6894b55c6a0673e4a83c9
LG-387_333_Aceton-bgnew.sp
DaRUS/FT-IR/NO-PI-3-COF/solvent stability/Unknown - 30.4 KB
Published Jan 29, 2024
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MD5: 965cb70790973b48500608d2c153388c
LG-387_333_DMF.csv
DaRUS/FT-IR/NO-PI-3-COF/solvent stability/Comma Separated Values - 52.0 KB
Published Jan 29, 2024
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MD5: 0d63f1b6d0b0ba11b86d76fd1a1a9e31
LG-387_333_DMF.sp
DaRUS/FT-IR/NO-PI-3-COF/solvent stability/Unknown - 30.4 KB
Published Jan 29, 2024
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MD5: 4f570eb8014371c6406ac7ced0cd2bf4
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