Replication data of B3 group for: "Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions"doi:10.18419/darus-2210DaRUS2022-02-211Kirchhof, Manuel, 2022, "Replication data of B3 group for: "Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions"", https://doi.org/10.18419/darus-2210, DaRUS, V1Replication data of B3 group for: "Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions"doi:10.18419/darus-2210Kirchhof, Manuel358283783 - SFB 1333DaRUSLaschat, SabineKirchhof, Manuel2021-10-21ChemistryAsymmetric CatalysisRhodium CatalysisAnion ExchangeAmphiphilic FilmC-C CouplingDiene LigandsKineticsLiquid ConfinementMicroemulsionIn this dataset HPLC (high performance liquid chromatography) chromatograms of the products of the rhodium-catalyzed 1,2-addition and NMR spectra of all prepared ligands, catalysts and catalysis products (NMR) are included. Furthermore, the NMR data of temperature and solvent dependent kinetics in dioxane and in microemulsions (Kinetiken) are listed.
Crystallographic data was published in Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC) as stated under related datasets.experimental dataanalytical dataStructure L2-H2: CCDC 2099410 doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28glx8">10.5517/ccdc.csd.cc28glx8</a><br/>Structure L1-H2: CCDC 2099412 doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28glzb">10.5517/ccdc.csd.cc28glzb</a><br/>Structure [Rh(L2)OTf]: CCDC 2099413 doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28gm0d">10.5517/ccdc.csd.cc28gm0d</a><br/>Structure [Rh(L2)OTs]: CCDC 2099414, <a href="https://doi.org/10.5517/ccdc.csd.cc28gm1f">10.5517/ccdc.csd.cc28gm1f</a><br/>Structure [Rh(L2)OAc]: CCDC 2099419, doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28gm6l">10.5517/ccdc.csd.cc28gm6l</a><br/>Structure [Rh(L2)PO2F2]: CCDC 2099420 doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28gm7m">10.5517/ccdc.csd.cc28gm7m</a><br/>Structure [[Rh(L2)OH2]SbF6 · CH2Cl2]: CCDC 2099421 doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28gm8n">10.5517/ccdc.csd.cc28gm8n</a>Manuel Kirchhof, Karina Abitaev, Abdulwahab Abouhaileh, Katrin Gugeler, Wolfgang Frey, Anna Zens, Johannes Kästner, Thomas Sottmann, Sabine Laschat. Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions. Chem. Eur. J. 2021, 68, 16853-16870.10.1002/chem.202102752Manuel Kirchhof, Karina Abitaev, Abdulwahab Abouhaileh, Katrin Gugeler, Wolfgang Frey, Anna Zens, Johannes Kästner, Thomas Sottmann, Sabine Laschat. Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions. Chem. Eur. J. 2021, 68, 16853-16870.[Rh(COD)Cl] in C8G1 ME (28).xpsapplication/vnd.ms-xpsdocument[Rh(L1)Cl] in C8G1,AOT ME (14,5).xpsapplication/vnd.ms-xpsdocument[Rh(L1)Cl] in C8G1,AOT ME (21,5).xpsapplication/vnd.ms-xpsdocument[Rh(L1)Cl] in C8G1,AOT ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L1)Cl] in C8G1,SDS ME (14,10).xpsapplication/vnd.ms-xpsdocument[Rh(L1)Cl] in C8G1,SDS ME (28,10).xpsapplication/vnd.ms-xpsdocument[Rh(L1)Cl] in C8G1,SDS ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)Cl]2 in C8G1,SDS ME (28,10).xpsapplication/vnd.ms-xpsdocument[Rh(L2)Cl]2 in C8G1,SDS ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1 ME (28).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,AOT ME (14,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,AOT ME (21,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,AOT ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,DTAB ME (28,10).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,SDS ME (14,10).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,SDS ME (28,10).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in C8G1,SDS ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in Toluol,H2O, 1 Äq AOT.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in Toluol,H2O, 1 Äq SDS.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in Toluol,H2O, 30 mg AOT.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] in Toluol,H2O, 30 mg SDS.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OAc] with 2 x cmc C8G1.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OH2]SbF6 in C8G1 ME (28).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OH2]SbF6 in C8G1,AOT ME (14,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OH2]SbF6 in C8G1,AOT ME (21,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OH2]SbF6 in C8G1,AOT ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OH2]SbF6 in dioxane.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTf] in C8G1 ME (28).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTf] in C8G1,AOT ME (14,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTf] in C8G1,AOT ME (21,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTf] in C8G1,AOT ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTf] in dioxane.xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1 ME (28).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1,AOT ME (14,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1,AOT ME (21,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1,AOT ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1,SDS ME (14,10).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1,SDS ME (28,10).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in C8G1,SDS ME (28,5).xpsapplication/vnd.ms-xpsdocument[Rh(L2)OTs] in dioxan.xpsapplication/vnd.ms-xpsdocument[Rh(L2)PO2F2] in C8G1 ME (28).xpsapplication/vnd.ms-xpsdocument[Rh(L2)PO2F2] in dioxane.xpsapplication/vnd.ms-xpsdocument2 x CMC at 50 °C with [Rh(L2)OAc].zipapplication/zipdioxane at 60 °C with [Rh(L2)OAc].zipapplication/zipgamma = 14 delta = 5 at 50 °C with [Rh(L2)OAc].zipapplication/zipgamma = 21 delta = 5 at 50 °C with [Rh(L2)OAc].zipapplication/zipgamma = 28 at 40 °C with [Rh(L2)OAc].zipapplication/zipgamma = 28 at 50 °C with [Rh(L2)OAc].zipapplication/zipgamma = 28 at 60 °C with [Rh(L2)OAc].zipapplication/zipgamma = 28 delta = 5 at 50 °C with [Rh(L2)OAc].zipapplication/zip3.zipapplication/zipL1-H2.zipapplication/zipL2-H2.zipapplication/zip[Rh(L2)AOT].zipapplication/zip[Rh(L2)OAc].zipapplication/zip[Rh(L2)OH2]SbF6.zipapplication/zip[Rh(L2)OTf].zipapplication/zip[Rh(L2)OTs].zipapplication/zip[Rh(L2)PO2F2].zipapplication/zip[Rh(L2)SDS].zipapplication/zipCounterion Exchange-1.zipapplication/zipHydrogenation Products.zipapplication/zip