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Part 1: Document Description
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Citation |
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Title: |
Replication Data for: "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement" |
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Identification Number: |
doi:10.18419/darus-1774 |
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Distributor: |
DaRUS |
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Date of Distribution: |
2021-05-05 |
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Version: |
1 |
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Bibliographic Citation: |
Beurer, Ann-Katrin; Kirchhof, Manuel; Bruckner, Johanna R.; Dyballa, Michael, 2021, "Replication Data for: "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement"", https://doi.org/10.18419/darus-1774, DaRUS, V1 |
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Citation |
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Title: |
Replication Data for: "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement" |
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Subtitle: |
Data of all participating research groups |
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Identification Number: |
doi:10.18419/darus-1774 |
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Authoring Entity: |
Beurer, Ann-Katrin (Institute of Technical Chemistry, University Stuttgart) |
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Kirchhof, Manuel (Institute of Organic Chemistry, University Stuttgart) |
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Bruckner, Johanna R. (Institute of Physical Chemistry, University Stuttgart) |
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Dyballa, Michael (Institute of Technical Chemistry, University Stuttgart) |
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Software used in Production: |
ASiQwin |
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Software used in Production: |
WinNMR |
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Software used in Production: |
NETZSCH Proteus - Thermal Analysis |
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Software used in Production: |
NETZSCH Measurement |
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Software used in Production: |
LCsolution |
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Software used in Production: |
TopSpin |
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Software used in Production: |
Chem3D |
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Software used in Production: |
OMNIC |
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Grant Number: |
358283783 - SFB 1333 |
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Distributor: |
DaRUS |
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Access Authority: |
Traa, Yvonne |
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Depositor: |
Beurer, Ann-Katrin |
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Date of Deposit: |
2021-04-08 |
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Holdings Information: |
https://doi.org/10.18419/darus-1774 |
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Study Scope |
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Keywords: |
Chemistry, spatially controlled functionalization, asymmetric catalysis, confinement |
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Abstract: |
The manuscript describes a method, which ensures a selective functionalization of the mesopore surface with a clickable linker and thus makes it possible to study confinement effects during catalyzed reactions. First, the silanol groups on the particle surface and in the pore entrances of the SBA-15 are passivated. By solvent extraction, the template is removed and afterwards the pore walls are functionalized with 3-azidopropyltriethoxysilane before the catalyst is clicked on the pore walls. In initial experiments of asymmetric Rh-catalyzed 1,2-addition, the performance of a catalyst clicked selectively on the mesopore walls is investigated. The data used for the manuscript are sorted by the respective characterization method.The data are named either according to the sample name, the entry or the figure in the paper. All data are raw data that can be processed with the corresponding software. |
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Methodology and Processing |
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Sources Statement |
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Data Access |
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Other Study Description Materials |
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Related Publications |
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Citation |
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Title: |
A.-K. Beurer, M. Kirchhof, J. R. Bruckner, W. Frey, A. Baro, M. Dyballa, F. Giesselmann, Y. Traa (2021), "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement", ChemCatChem |
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Identification Number: |
10.1002/cctc.202100229 |
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Bibliographic Citation: |
A.-K. Beurer, M. Kirchhof, J. R. Bruckner, W. Frey, A. Baro, M. Dyballa, F. Giesselmann, Y. Traa (2021), "Efficient and Spatially Controlled Functionalization of SBA-15 and Initial Results in Asymmetric Rh-Catalyzed 1,2-Additions under Confinement", ChemCatChem |
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Label: |
Masse von Supernatant - Ligandenstabilität.zip |
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Notes: |
application/zip |
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Label: |
Röntgen-Daten_Verbindungen.zip |
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Text: |
X-ray of the linkers |
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Notes: |
application/zip |
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Background.zip |
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Notes: |
application/zip |
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Figure 3a.zip |
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Text: |
SBA-15-ex-E-p-in6 |
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Notes: |
application/zip |
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Label: |
Figure 4a 3b.zip |
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Text: |
SBA-15-ex+in |
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Notes: |
application/zip |
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Figure 4b.zip |
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Text: |
SBA-15-ex+in-2a |
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Notes: |
application/zip |
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Label: |
DTA_SBA-15-as-synthesized.txt |
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Notes: |
text/plain |
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Label: |
DTA_SBA-15-calcined_air.txt |
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Notes: |
text/plain |
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Label: |
DTA_SBA-15-calcined_N2.txt |
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Notes: |
text/plain |
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Label: |
DTA_SBA-15-ex+in-HMDS_air.txt |
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Notes: |
text/plain |
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DTA_SBA-15-ex+in-HMDS_N2.txt |
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Notes: |
text/plain |
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DTA_SBA-15-ex+in-HMDS_PT-N2.txt |
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Notes: |
text/plain |
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DTA_SBA-15-ex-E-p.txt |
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Notes: |
text/plain |
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Label: |
DTA_SBA-15-ex-E.txt |
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Notes: |
text/plain |
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Label: |
DTA_SBA-15-ex.txt |
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Notes: |
text/plain |
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Label: |
Linker 2a.zip |
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Samples with Linker 2a |
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Notes: |
application/zip |
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Label: |
Linker 2c.zip |
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Text: |
Samples with Linker 2c |
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Notes: |
application/zip |
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Stability ex.zip |
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Experiments regarding the stability of the functionalized external surface |
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Notes: |
application/zip |
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Label: |
2a.xps |
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Notes: |
application/vnd.ms-xpsdocument |
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2b.xps |
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application/vnd.ms-xpsdocument |
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2c.xps |
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application/vnd.ms-xpsdocument |
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3b.xps |
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Notes: |
application/vnd.ms-xpsdocument |
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3c und CuSO4 und Kieselgel.xps |
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application/vnd.ms-xpsdocument |
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3c und CuSO4.xps |
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application/vnd.ms-xpsdocument |
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3c.xps |
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application/vnd.ms-xpsdocument |
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SBA-15-ex+in-2c (0.42 mmol).xps |
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Notes: |
application/vnd.ms-xpsdocument |
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SBA-15-ex-2a (0.41 mmol).xps |
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application/vnd.ms-xpsdocument |
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SBA-15-in-2c (0.034 mmol).xps |
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application/vnd.ms-xpsdocument |
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SBA-15-in-2c (0.090 mmol).xps |
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application/vnd.ms-xpsdocument |
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SBA-15-in-2c (0.123 mmol).xps |
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application/vnd.ms-xpsdocument |
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first cycle.xps |
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application/vnd.ms-xpsdocument |
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second cycle.xps |
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Notes: |
application/vnd.ms-xpsdocument |
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Linker 2a.xlsx |
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Text: |
Samples with Linker 2a |
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Notes: |
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet |
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Linker 2c.xlsx |
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Text: |
Samplex with Linker 2c |
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Notes: |
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet |
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Label: |
N2_SBA-15-as-synthesized.RAW |
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Notes: |
application/octet-stream |
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N2_SBA-15-calcined.RAW |
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application/octet-stream |
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Label: |
N2_SBA-15-EDTA-Wash.RAW |
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application/octet-stream |
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Label: |
N2_SBA-15-EDTA-Wash_1.Katalyse.RAW |
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application/octet-stream |
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Label: |
N2_SBA-15-ex-control.RAW |
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application/octet-stream |
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N2_SBA-15-ex-E-in6.RAW |
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application/octet-stream |
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N2_SBA-15-ex-E-p-in24.RAW |
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application/octet-stream |
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N2_SBA-15-ex-E-p-in6.RAW |
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application/octet-stream |
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N2_SBA-15-ex-E-p-in72.RAW |
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Notes: |
application/octet-stream |
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N2_SBA-15-ex-E-p.RAW |
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Notes: |
application/octet-stream |
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Label: |
N2_SBA-15-ex-E.RAW |
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Notes: |
application/octet-stream |
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Label: |
N2_SBA-15-ex.RAW |
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Notes: |
application/octet-stream |
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2a.zip |
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Notes: |
application/zip |
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2b.zip |
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Notes: |
application/zip |
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2c.zip |
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Notes: |
application/zip |
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3a.zip |
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Notes: |
application/zip |
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3b.zip |
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Notes: |
application/zip |
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3c.zip |
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Notes: |
application/zip |
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4.zip |
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application/zip |
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7.zip |
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Notes: |
application/zip |
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background.pdh |
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Notes: |
application/octet-stream |
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Cholesteryl_Palmitate.pdh |
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application/octet-stream |
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Cholesteryl_Palmitate_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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SAXS_SBA-15-ex-E-p-in72_after_treatment_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA-15-es-E-p-in72_after_treatment.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-as-synthesized.pdh |
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Notes: |
application/octet-stream |
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SBA15-as-synthesized_deconvoluted.pdh |
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application/octet-stream |
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SBA15-calcined.pdh |
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application/octet-stream |
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SBA15-calcined_deconvoluted.pdh |
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application/octet-stream |
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SBA15-ex-E-in6.pdh |
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Notes: |
application/octet-stream |
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SBA15-ex-E-in6_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p-in24-3c.pdh |
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Notes: |
application/octet-stream |
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SBA15-ex-E-p-in24-3c_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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SBA15-ex-E-p-in24.pdh |
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application/octet-stream |
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SBA15-ex-E-p-in24_deconvoluted.pdh |
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application/octet-stream |
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SBA15-ex-E-p-in6-3c.pdh |
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application/octet-stream |
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Label: |
SBA15-ex-E-p-in6-3c_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p-in6.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p-in6_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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SBA15-ex-E-p-in72-3c.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p-in72-3c_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p-in72.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p-in72_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex-E-p_deconvoluted.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex.pdh |
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Notes: |
application/octet-stream |
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Label: |
SBA15-ex_deconvoluted.pdh |
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Notes: |
application/octet-stream |