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Part 1: Document Description
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Citation |
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Title: |
Replication Data for: A Hard Templating Approach to Functional Mesoporous Poly(norborn-2-ene)-Based Monolithic Supports |
Identification Number: |
doi:10.18419/darus-2243 |
Distributor: |
DaRUS |
Date of Distribution: |
2021-11-30 |
Version: |
1 |
Bibliographic Citation: |
Acikalin, Hande; Ziegler, Felix; Buchmeiser, Michael, 2021, "Replication Data for: A Hard Templating Approach to Functional Mesoporous Poly(norborn-2-ene)-Based Monolithic Supports", https://doi.org/10.18419/darus-2243, DaRUS, V1, UNF:6:p82WcxeApActls7MElmKaA== [fileUNF] |
Citation |
|
Title: |
Replication Data for: A Hard Templating Approach to Functional Mesoporous Poly(norborn-2-ene)-Based Monolithic Supports |
Identification Number: |
doi:10.18419/darus-2243 |
Authoring Entity: |
Acikalin, Hande (Universität Stuttgart) |
Ziegler, Felix (Universität Stuttgart) |
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Buchmeiser, Michael (Universität Stuttgart) |
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Grant Number: |
358283783 - SFB 1333 |
Distributor: |
DaRUS |
Access Authority: |
Buchmeiser, Michael |
Depositor: |
Acikalin, Hande |
Date of Deposit: |
2021-11-25 |
Holdings Information: |
https://doi.org/10.18419/darus-2243 |
Study Scope |
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Keywords: |
Chemistry, Ring-opening metathesis polymerization (LCSH), Hard templating, Monolithic structures |
Topic Classification: |
Polymers |
Abstract: |
All primary data files of measurements and processed data of the journal article mentioned under related publications from Buchmeiser group can be found here. Further experimental for reproduction of experiments can be found in the <a href="https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fmacp.202100247&file=macp202100247-sup-0001-SuppMat.pdf">Supporting Information</a>. We report on the first ROMP-derived, poly(norborn-2-ene)-based monolithic supports with such tailored mesoporosity using a SiO2 nanowire (SNW) based hard templating approach that stongly differs form other hard templating approaches in that it provides access to defined mesopores. The resulting macroporous/mesoporous polymeric monoliths have a tailored mesoporosity in the 10–15 nm regime, transport pores in the micrometer range and allow for high linear flow rates (>2 mm s−1) at low back pressure (<6 bar). Together with the functional (OH) groups present, which can be used for catalyst immobilization, this morphological control over the meso- and macroporous structure offers access for use as catalytic microreactors. The hard templating process in combination with the solvent-induced phase separation (SIPS) process offers access to hybrid ROMP-derived monolithic structures. The surface-modified SNWs are incorporated into the structure-forming microglobule`s surface and can be removed with the aid of HF. By this approach, an increased mesoporosity with pore dimensions in the range of 5–30 nm, corresponding to the SiO2 nanowire diameter, is observed. |
Methodology and Processing |
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Sources Statement |
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Data Access |
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Other Study Description Materials |
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Related Materials |
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Felix Ziegler, Thomas Roider, Markus Pyschik, Christian P. Haas, Dongren Wang, Ulrich Tallarek, and Michael R. Buchmeiser. Olefin Ring‐closing Metathesis under Spatial Confinement and Continuous Flow. ChemCatChem, 2021, 13, 2234-2241. doi: <a href="https://doi.org/10.1002/cctc.202001993">10.1002/cctc.202001993</a> |
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Related Publications |
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Citation |
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Title: |
H. Acikalin, F. Ziegler, D. Wang, M. R. Buchmeiser, A Hard Templating Approach to Functional Mesoporous Poly(norborn-2-ene)-Based Monolithic Supports. Macromolecular Chemistry and Physics, 2021, 222, 2100247. |
Identification Number: |
10.1002/macp.202100247 |
Bibliographic Citation: |
H. Acikalin, F. Ziegler, D. Wang, M. R. Buchmeiser, A Hard Templating Approach to Functional Mesoporous Poly(norborn-2-ene)-Based Monolithic Supports. Macromolecular Chemistry and Physics, 2021, 222, 2100247. |
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Summary Statistics: Max. 1682.4; Min. 8.9; Mean 410.9428571428572; Valid 7.0; StDev 634.6646801189399 Variable Format: numeric Notes: UNF:6:V+7mUv/ZDAwUXTsAOldkeg== |
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Summary Statistics: StDev 63.46646801189399; Valid 7.0; Min. 0.89; Max. 168.24; Mean 41.09428571428572 Variable Format: numeric Notes: UNF:6:Nec0zCyFpHPV3vgCvT3mQQ== |
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Summary Statistics: Valid 7.0; StDev 287.7354108667661; Min. 1525.0; Max. 2348.0; Mean 1828.0 Variable Format: numeric Notes: UNF:6:G4N4mL48eajMDiT6G5mnuA== |
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Summary Statistics: Min. 1.08724399363983; Max. 2.67694630836143; Mean 1.7148088072948486; StDev 0.5599663620235973; Valid 7.0 Variable Format: numeric Notes: UNF:6:Mhb/4FxhkXvAszkdInWHwg== |
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BU1008_10.tif |
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BU1102_EDX_Mapping_10kV.pdf |
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EDX - 1.pdf |
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application/pdf |
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XLSX version of M0.tab |
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XLSX version of M1a.tab |
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XLSX version of M1b.tab |
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application/vnd.openxmlformats-officedocument.spreadsheetml.sheet |
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XLSX version of M2a.tab |
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application/vnd.openxmlformats-officedocument.spreadsheetml.sheet |
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M2b.xlsx |
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XLSX version of M2b.tab |
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application/vnd.openxmlformats-officedocument.spreadsheetml.sheet |