Data for: "Origin and Use of Hydroxyl Group Tolerance in Cationic Molybdenum Imido Alkylidene N‐Heterocyclic Carbene Catalysts"doi:10.18419/darus-1702DaRUS2021-04-221Schowner, Roman; Elser, Iris; Benedikter, Mathis, 2021, "Data for: "Origin and Use of Hydroxyl Group Tolerance in Cationic Molybdenum Imido Alkylidene N‐Heterocyclic Carbene Catalysts"", https://doi.org/10.18419/darus-1702, DaRUS, V1Data for: "Origin and Use of Hydroxyl Group Tolerance in Cationic Molybdenum Imido Alkylidene N‐Heterocyclic Carbene Catalysts"doi:10.18419/darus-1702Schowner, RomanElser, IrisBenedikter, Mathis358283783 - SFB 1333DaRUSBuchmeiser, MichaelBenedikter, Mathis2021-03-11ChemistryMetal ComplexMetathesisCatalysisTransition MetalMolybdenumInorganic ChemistryPrimary data files related to the publication. Procedures, recation conditions and used analytical equipment is discussed in detail in the experimental section or the supporting information of the paper. Productivities in olefin metathesis reactions were examined via gas-chromatography / mass spectrometry (GC-MS) analysis and can be found in the GC-MS folder. Furthermore, the GC-MS folder contains an Excel-file in which the names of the data files are listed and assigned to table entries in the publication. However, the data set does not contain the complete GC-MS data. Novel complexes were examined via nuclear magnetic resonance (NMR) spectroscopy and the spectra can be found in NMR folder. The NMR folder also contains NMR experiments mentioned in the paper and shown in the Supplementary Information. NMR Spectra are named according to the numbering in the publication. All crystal data mentioned in the paper can be found in the related datasets.NMR spectra were processed with MestreNova. GC-MS data was processed with Agilent MassHunter.Crystal data for 3a:<br/>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1946042: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23b0k1">DOI: 10.5517/ccdc.csd.cc23b0k1</a><br/>Crystal data for 4a*H2O:<br/>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1946041: Experimental Crystal Structure Determination, 2019, DOI:<a href="https://doi.org/10.5517/ccdc.csd.cc23b0j0">DOI: 10.5517/ccdc.csd.cc23b0j0</a><br/>Crystal data for 4d:<br/>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1959263: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23rs1q">DOI: 10.5517/ccdc.csd.cc23rs1q</a><br/>Crystal data for 5d: <br/>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1959261: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23rrzm">DOI: 10.5517/ccdc.csd.cc23rrzm</a><br/>Crystal data for 5d-MeCN:<br/>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1959260: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23rryl">DOI: 10.5517/ccdc.csd.cc23rryl</a><br/>Crystal data for 6:<br/>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1946043: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23b0l2">DOI: 10.5517/ccdc.csd.cc23b0l2</a><br/>Crystal data for 15b:<br>
Roman Schowner, Iris Elser, Mathis Benedikter, Mohasin Momin, Wolfgang Frey, Tanja Schneck, Laura Stöhr, Michael R. Buchmeiser CCDC 1959262: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23rs0p">DOI: 10.5517/ccdc.csd.cc23rs0p</a>R. Schowner, I. Elser, M. Benedikter, M. Momin, W. Frey, T. Schneck, L. Stöhr, M. R. Buchmeiser, Origin and Use of Hydroxyl Group Tolerance in Cationic Molybdenum Imido Alkylidene N‐Heterocyclic Carbene Catalysts. Angew. Chem. Int. Ed. 2020, 59, 951.10.1002/anie.201913322R. Schowner, I. Elser, M. Benedikter, M. Momin, W. Frey, T. Schneck, L. Stöhr, M. R. Buchmeiser, Origin and Use of Hydroxyl Group Tolerance in Cationic Molybdenum Imido Alkylidene N‐Heterocyclic Carbene Catalysts. Angew. Chem. Int. Ed. 2020, 59, 951.14.zipapplication/zip3b.zipapplication/zip3c.zipapplication/zip3d.zipapplication/zip4b.zipapplication/zip4c.zipapplication/zip4D.zipapplication/zipsample names.xlsxapplication/vnd.openxmlformats-officedocument.spreadsheetml.sheetpure compounds.zipapplication/zipstability tests.zipapplication/zip