Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes (ICPSR doi:10.18419/darus-1705)

View:

Part 1: Document Description
Part 2: Study Description
Part 5: Other Study-Related Materials
Entire Codebook

(external link)

Document Description

Citation

Title:

Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes

Identification Number:

doi:10.18419/darus-1705

Distributor:

DaRUS

Date of Distribution:

2021-04-09

Version:

1

Bibliographic Citation:

Schowner, Roman; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes", https://doi.org/10.18419/darus-1705, DaRUS, V1

Study Description

Citation

Title:

Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes

Subtitle:

NMR data and link to crystallographic data

Identification Number:

doi:10.18419/darus-1705

Authoring Entity:

Schowner, Roman (Universität Stuttgart)

Frey, Wolfgang (Universität Stuttgart)

Buchmeiser, Michael (Universität Stuttgart)

Grant Number:

358283783 - SFB 1333

Grant Number:

none

Grant Number:

BU 2174/19‐1

Distributor:

DaRUS

Access Authority:

Buchmeiser, Michael

Depositor:

Rüthlein, Elisabeth

Date of Deposit:

2021-04-07

Study Scope

Keywords:

Chemistry, molybdenum, carbene, metathesis, synthesis, ligand

Abstract:

Data on novel synthetic approaches to molybdenum imido alkylidene N‐heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl‐substituted imido ligands, highly basic 6‐Mes (6‐Mes = 1,3‐dimesityl‐3,4,5,6‐tetrahydropyrimidin‐2‐ylidene) NHC ligands and the preparation of the first representatives of cationic 14‐electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands. <br/> Synthetic approaches and data are presented in the research article. <br/> Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added. Crystallographic data was published in the CCDC as stated under related datasets . <br/> This dataset contains the following data types: NMR data (raw data, Bruker-zip files)

Kind of Data:

Experimental Data

Kind of Data:

synthetic study for catalyst preparation

Methodology and Processing

Sources Statement

Data Access

Notes:

CC BY Waiver

Other Study Description Materials

Related Studies

CCDC <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pxr">1879434</a> (for 2c), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pzt">1879436</a> (for 8c), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pvp">1879432</a> (for 10), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pys">1879435</a> (for 19b), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc214nvq">1881323</a> (for 20b), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pwq">1879433</a> (for 24a), and <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212ptn">1879431</a> (for 33) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from <a href="https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.1002/ejic.201900021">The Cambridge Crystallographic Data Centre</a>.

Related Publications

Citation

Identification Number:

10.1002/ejic.201900021

Bibliographic Citation:

Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922.

Other Study-Related Materials

Label:

11b - RS-773.zip

Notes:

application/zip

Other Study-Related Materials

Label:

12 - RS-766.zip

Notes:

application/zip

Other Study-Related Materials

Label:

14a - RS-708.zip

Notes:

application/zip

Other Study-Related Materials

Label:

14b - RS-1015.zip

Notes:

application/zip

Other Study-Related Materials

Label:

14c - RS-817.zip

Notes:

application/zip

Other Study-Related Materials

Label:

15 - RS-1024.zip

Notes:

application/zip

Other Study-Related Materials

Label:

16 - RS-1051.zip

Notes:

application/zip

Other Study-Related Materials

Label:

17 - RS-1034.zip

Notes:

application/zip

Other Study-Related Materials

Label:

18a - RS-903.zip

Notes:

application/zip

Other Study-Related Materials

Label:

18b - RS-924.zip

Notes:

application/zip

Other Study-Related Materials

Label:

18c - RS-923.zip

Notes:

application/zip

Other Study-Related Materials

Label:

19a - RS-926.zip

Notes:

application/zip

Other Study-Related Materials

Label:

19b - RS-925.zip

Notes:

application/zip

Other Study-Related Materials

Label:

19c - RS-992.zip

Notes:

application/zip

Other Study-Related Materials

Label:

20a - RS-954.zip

Notes:

application/zip

Other Study-Related Materials

Label:

20b - RS-1029.zip

Notes:

application/zip

Other Study-Related Materials

Label:

20c - RS-1031.zip

Notes:

application/zip

Other Study-Related Materials

Label:

20d - RS-1039.zip

Notes:

application/zip

Other Study-Related Materials

Label:

22a - RS-823.zip

Notes:

application/zip

Other Study-Related Materials

Label:

23a - RS-878.zip

Notes:

application/zip

Other Study-Related Materials

Label:

24a - RS-881.zip

Notes:

application/zip

Other Study-Related Materials

Label:

25a - RS-911.zip

Notes:

application/zip

Other Study-Related Materials

Label:

27 - RS-871.zip

Notes:

application/zip

Other Study-Related Materials

Label:

28 - RS-873.zip

Notes:

application/zip

Other Study-Related Materials

Label:

29 - RS-876.zip

Notes:

application/zip

Other Study-Related Materials

Label:

2a-2b - RS-929.zip

Notes:

application/zip

Other Study-Related Materials

Label:

32 - RS-524.zip

Notes:

application/zip

Other Study-Related Materials

Label:

33 - RS-545.zip

Notes:

application/zip

Other Study-Related Materials

Label:

35 - RS-953.zip

Notes:

application/zip

Other Study-Related Materials

Label:

36 - RS-958.zip

Notes:

application/zip

Other Study-Related Materials

Label:

37 - RS-969.zip

Notes:

application/zip

Other Study-Related Materials

Label:

4a-4b - RS-1008.zip

Notes:

application/zip

Other Study-Related Materials

Label:

8a - RS-789.zip

Notes:

application/zip

Other Study-Related Materials

Label:

8b - RS-760.zip

Notes:

application/zip

Other Study-Related Materials

Label:

8c - RS-804.zip

Notes:

application/zip

Other Study-Related Materials

Label:

9-10-11a - RS-758.zip

Notes:

application/zip

Other Study-Related Materials

Label:

Strukturen.pdf

Text:

Overview of all structures for which NMR data is being provided

Notes:

application/pdf