Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexesdoi:10.18419/darus-1705DaRUS2021-04-091Schowner, Roman; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes", https://doi.org/10.18419/darus-1705, DaRUS, V1Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene ComplexesNMR data and link to crystallographic datadoi:10.18419/darus-1705Schowner, RomanFrey, WolfgangBuchmeiser, Michael358283783 - SFB 1333noneBU 2174/19‐1DaRUSBuchmeiser, MichaelRüthlein, Elisabeth2021-04-07ChemistrymolybdenumcarbenemetathesissynthesisligandData on novel synthetic approaches to molybdenum imido alkylidene N‐heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl‐substituted imido ligands, highly basic 6‐Mes (6‐Mes = 1,3‐dimesityl‐3,4,5,6‐tetrahydropyrimidin‐2‐ylidene) NHC ligands and the preparation of the first representatives of cationic 14‐electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands. <br/>
Synthetic approaches and data are presented in the research article. <br/>
Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added.
Crystallographic data was published in the CCDC as stated under related datasets . <br/>
This dataset contains the following data types: NMR data (raw data, Bruker-zip files)Experimental Datasynthetic study for catalyst preparationCCDC <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pxr">1879434</a> (for 2c), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pzt">1879436</a> (for 8c), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pvp">1879432</a> (for 10), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pys">1879435</a> (for 19b), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc214nvq">1881323</a> (for 20b), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pwq">1879433</a> (for 24a), and <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212ptn">1879431</a> (for 33) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from <a href="https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.1002/ejic.201900021">The Cambridge Crystallographic Data Centre</a>.Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922.10.1002/ejic.201900021Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922.Strukturen.pdfOverview of all structures for which NMR data is being providedapplication/pdf11b - RS-773.zipapplication/zip12 - RS-766.zipapplication/zip14a - RS-708.zipapplication/zip14b - RS-1015.zipapplication/zip14c - RS-817.zipapplication/zip15 - RS-1024.zipapplication/zip16 - RS-1051.zipapplication/zip17 - RS-1034.zipapplication/zip18a - RS-903.zipapplication/zip18b - RS-924.zipapplication/zip18c - RS-923.zipapplication/zip19a - RS-926.zipapplication/zip19b - RS-925.zipapplication/zip19c - RS-992.zipapplication/zip20a - RS-954.zipapplication/zip20b - RS-1029.zipapplication/zip20c - RS-1031.zipapplication/zip20d - RS-1039.zipapplication/zip22a - RS-823.zipapplication/zip23a - RS-878.zipapplication/zip24a - RS-881.zipapplication/zip25a - RS-911.zipapplication/zip27 - RS-871.zipapplication/zip28 - RS-873.zipapplication/zip29 - RS-876.zipapplication/zip2a-2b - RS-929.zipapplication/zip32 - RS-524.zipapplication/zip33 - RS-545.zipapplication/zip35 - RS-953.zipapplication/zip36 - RS-958.zipapplication/zip37 - RS-969.zipapplication/zip4a-4b - RS-1008.zipapplication/zip8a - RS-789.zipapplication/zip8b - RS-760.zipapplication/zip8c - RS-804.zipapplication/zip9-10-11a - RS-758.zipapplication/zip