Replication Data for: Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route (ICPSR doi:10.18419/darus-1670)

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Document Description

Citation

Title:

Replication Data for: Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route

Identification Number:

doi:10.18419/darus-1670

Distributor:

DaRUS

Date of Distribution:

2021-03-19

Version:

1

Bibliographic Citation:

Musso, Janis; Benedikter, Mathis; Gebel, Paul; Elser, Iris; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication Data for: Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route", https://doi.org/10.18419/darus-1670, DaRUS, V1

Study Description

Citation

Title:

Replication Data for: Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route

Identification Number:

doi:10.18419/darus-1670

Authoring Entity:

Musso, Janis (Universität Stuttgart)

Benedikter, Mathis (Universität Stuttgart)

Gebel, Paul (Universität Stuttgart)

Elser, Iris (Universität Stuttgart)

Frey, Wolfgang (Universität Stuttgart)

Buchmeiser, Michael (Universität Stuttgart)

Grant Number:

U2174/22-1

Grant Number:

58283783-CRC1333

Distributor:

DaRUS

Access Authority:

Buchmeiser, Michael

Depositor:

Musso, Janis

Date of Deposit:

2021-03-09

Study Scope

Keywords:

Chemistry, tungsten, alkylidene group, isocyanates

Abstract:

A general route to tungsten(VI) imido alkylidene bispyrrolide complexes via the extrusion of CO2 from the reaction of one equivalent of an aryl isocyanate with WOCl4 to form the corresponding imido complexes is reported. The Dataset contains the NMR spectra of figures S1 and S2 (zip-file 1 and 2) and NMR spectra of all compounds (zip-file 3). The detailed procedure for the synthesis of compunds as well as information about the used analytical equipment can be found in the supporting information of the paper.

Methodology and Processing

Sources Statement

Data Access

Notes:

CC BY Waiver

Other Study Description Materials

Related Studies

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Single Crystal x-ray structure of compund W-13: <a href="https://doi.org/10.5517/ccdc.csd.cc25jnbq">DOI: 10.5517/ccdc.csd.cc25jnbq</a>

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Related Publications

Citation

Identification Number:

10.1021/acs.organomet.0c00435

Bibliographic Citation:

Janis V. Musso, Mathis J. Benedikter, Paul Gebel, Iris Elser, Wolfgang Frey, and Michael R. Buchmeiser. Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route. Organometallics 2020 39 (17), 3072-3076

Other Study-Related Materials

Label:

Figure S1.zip

Notes:

application/zip

Other Study-Related Materials

Label:

Figure S2.zip

Notes:

application/zip

Other Study-Related Materials

Label:

spectra of compounds.zip

Notes:

application/zip