Data for: "Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts" (ICPSR doi:10.18419/darus-1698)

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Part 2: Study Description
Part 5: Other Study-Related Materials
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Document Description

Citation

Title:

Data for: "Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts"

Identification Number:

doi:10.18419/darus-1698

Distributor:

DaRUS

Date of Distribution:

2021-04-22

Version:

1

Bibliographic Citation:

Benedikter, Mathis, 2021, "Data for: "Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts"", https://doi.org/10.18419/darus-1698, DaRUS, V1

Study Description

Citation

Title:

Data for: "Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts"

Identification Number:

doi:10.18419/darus-1698

Authoring Entity:

Benedikter, Mathis (Universität Stuttgart)

Grant Number:

358283783 - SFB 1333

Distributor:

DaRUS

Access Authority:

Buchmeiser, Michael

Depositor:

Benedikter, Mathis

Date of Deposit:

2021-03-11

Study Scope

Keywords:

Chemistry, metal complex, metathesis, catalysis, transition metal, molybdenum, tungsten

Topic Classification:

inorganic chemistry

Abstract:

All primary data files related to the publication. Procedures, recation conditions and used analytical equipment is discussed in detail in the experimental section or the supporting information of the paper. Productivities in olefin metathesis reactions were examined via gas-chromatography / mass spectrometry (GC-MS) analysis and can be found in the GC-MS folder. Furthermore, the GC-MS folder contains an Excel-file in which the names of the data files are listed and assigned to table entries in the publication. Novel complexes were examined via nuclear magnetic resonance (NMR) spectroscopy and the spectra can be found in NMR folder. The NMR folder also contains NMR experiments mentioned in the paper and shown in the Supplementary Information. NMR Spectra are named according to the numbering in the publication. All crystal data mentioned in the paper can be found in the related datasets. Size exclusion chromatography (SEC) data are provided as text-files and can be plotted with software such as MS Excel.

Notes:

NMR spectra were processed with MestreNova. GC-MS data was processed with Agilent MassHunter.

Methodology and Processing

Sources Statement

Data Access

Notes:

CC BY Waiver

Other Study Description Materials

Related Studies

CCDC 2023958 (W-13, <a href="https://doi.org/10.5517/ccdc.csd.cc25y2z6">DOI: 10.5517/ccdc.csd.cc25y2z6</a>)

CCDC 2023959 (W-14, <a href="https://doi.org/10.5517/ccdc.csd.cc25y308">DOI: 10.5517/ccdc.csd.cc25y308</a>)

Related Publications

Citation

Identification Number:

10.1002/anie.202011666

Bibliographic Citation:

M. J. Benedikter, J. V. Musso, W. Frey, R. Schowner, M. R. Buchmeiser, Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts. Angew. Chem. Int. Ed. 2021, 60, 1374.

Other Study-Related Materials

Label:

air-stability experiments.zip

Notes:

application/zip

Other Study-Related Materials

Label:

kinetics.zip

Notes:

application/zip

Other Study-Related Materials

Label:

NMR experiments.zip

Notes:

application/zip

Other Study-Related Materials

Label:

poly(M1-Mo03-MeCN).TXT

Text:

column 1: intensity of the RI signal [a.u.]; column 2: time [min]

Notes:

text/plain

Other Study-Related Materials

Label:

poly(M1-Mo03).TXT

Text:

column 1: intensity of the RI signal [a.u.] column 2: time [min]

Notes:

text/plain

Other Study-Related Materials

Label:

poly(M1-Mo04-MeCN).TXT

Text:

column 1: intensity of the RI signal [a.u.] column 2: time [min]

Notes:

text/plain

Other Study-Related Materials

Label:

poly(M1-Mo04).TXT

Text:

column 1: intensity of the RI signal [a.u.] column 2: time [min]

Notes:

text/plain

Other Study-Related Materials

Label:

polymerizations.zip

Notes:

application/zip

Other Study-Related Materials

Label:

productivities.zip

Notes:

application/zip

Other Study-Related Materials

Label:

pure compounds.zip

Notes:

application/zip

Other Study-Related Materials

Label:

sample names.xlsx

Notes:

application/vnd.openxmlformats-officedocument.spreadsheetml.sheet