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Part 1: Document Description
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Citation |
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Title: |
Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes |
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Identification Number: |
doi:10.18419/darus-1705 |
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Distributor: |
DaRUS |
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Date of Distribution: |
2021-04-09 |
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Version: |
1 |
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Bibliographic Citation: |
Schowner, Roman; Frey, Wolfgang; Buchmeiser, Michael, 2021, "Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes", https://doi.org/10.18419/darus-1705, DaRUS, V1 |
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Citation |
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Title: |
Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes |
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Subtitle: |
NMR data and link to crystallographic data |
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Identification Number: |
doi:10.18419/darus-1705 |
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Authoring Entity: |
Schowner, Roman (Universität Stuttgart) |
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Frey, Wolfgang (Universität Stuttgart) |
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Buchmeiser, Michael (Universität Stuttgart) |
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Grant Number: |
358283783 - SFB 1333 |
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Grant Number: |
none |
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Grant Number: |
BU 2174/19‐1 |
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Distributor: |
DaRUS |
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Access Authority: |
Buchmeiser, Michael |
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Depositor: |
Rüthlein, Elisabeth |
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Date of Deposit: |
2021-04-07 |
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Holdings Information: |
https://doi.org/10.18419/darus-1705 |
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Study Scope |
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Keywords: |
Chemistry, molybdenum, carbene, metathesis, synthesis, ligand |
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Abstract: |
Data on novel synthetic approaches to molybdenum imido alkylidene N‐heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl‐substituted imido ligands, highly basic 6‐Mes (6‐Mes = 1,3‐dimesityl‐3,4,5,6‐tetrahydropyrimidin‐2‐ylidene) NHC ligands and the preparation of the first representatives of cationic 14‐electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands. <br/> Synthetic approaches and data are presented in the research article. <br/> Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added. Crystallographic data was published in the CCDC as stated under related datasets . <br/> This dataset contains the following data types: NMR data (raw data, Bruker-zip files) |
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Kind of Data: |
Experimental Data |
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Kind of Data: |
synthetic study for catalyst preparation |
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Methodology and Processing |
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Sources Statement |
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Data Access |
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Other Study Description Materials |
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Related Studies |
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CCDC <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pxr">1879434</a> (for 2c), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pzt">1879436</a> (for 8c), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pvp">1879432</a> (for 10), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pys">1879435</a> (for 19b), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc214nvq">1881323</a> (for 20b), <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212pwq">1879433</a> (for 24a), and <a href="https://dx.doi.org/10.5517/ccdc.csd.cc212ptn">1879431</a> (for 33) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from <a href="https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.1002/ejic.201900021">The Cambridge Crystallographic Data Centre</a>. |
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Related Publications |
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Citation |
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Title: |
Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922. |
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Identification Number: |
10.1002/ejic.201900021 |
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Bibliographic Citation: |
Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922. |
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Label: |
Strukturen.pdf |
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Text: |
Overview of all structures for which NMR data is being provided |
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Notes: |
application/pdf |
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Label: |
11b - RS-773.zip |
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Notes: |
application/zip |
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Label: |
12 - RS-766.zip |
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Notes: |
application/zip |
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Label: |
14a - RS-708.zip |
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Notes: |
application/zip |
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Label: |
14b - RS-1015.zip |
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Notes: |
application/zip |
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Label: |
14c - RS-817.zip |
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Notes: |
application/zip |
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Label: |
15 - RS-1024.zip |
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Notes: |
application/zip |
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Label: |
16 - RS-1051.zip |
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Notes: |
application/zip |
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Label: |
17 - RS-1034.zip |
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Notes: |
application/zip |
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Label: |
18a - RS-903.zip |
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Notes: |
application/zip |
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Label: |
18b - RS-924.zip |
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Notes: |
application/zip |
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Label: |
18c - RS-923.zip |
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Notes: |
application/zip |
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Label: |
19a - RS-926.zip |
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Notes: |
application/zip |
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Label: |
19b - RS-925.zip |
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Notes: |
application/zip |
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Label: |
19c - RS-992.zip |
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Notes: |
application/zip |
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Label: |
20a - RS-954.zip |
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Notes: |
application/zip |
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Label: |
20b - RS-1029.zip |
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Notes: |
application/zip |
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Label: |
20c - RS-1031.zip |
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Notes: |
application/zip |
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Label: |
20d - RS-1039.zip |
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Notes: |
application/zip |
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Label: |
22a - RS-823.zip |
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Notes: |
application/zip |
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Label: |
23a - RS-878.zip |
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Notes: |
application/zip |
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Label: |
24a - RS-881.zip |
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Notes: |
application/zip |
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Label: |
25a - RS-911.zip |
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Notes: |
application/zip |
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Label: |
27 - RS-871.zip |
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Notes: |
application/zip |
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Label: |
28 - RS-873.zip |
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Notes: |
application/zip |
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Label: |
29 - RS-876.zip |
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Notes: |
application/zip |
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Label: |
2a-2b - RS-929.zip |
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Notes: |
application/zip |
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32 - RS-524.zip |
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Notes: |
application/zip |
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Label: |
33 - RS-545.zip |
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Notes: |
application/zip |
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Label: |
35 - RS-953.zip |
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Notes: |
application/zip |
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Label: |
36 - RS-958.zip |
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Notes: |
application/zip |
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Label: |
37 - RS-969.zip |
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Notes: |
application/zip |
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Label: |
4a-4b - RS-1008.zip |
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Notes: |
application/zip |
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Label: |
8a - RS-789.zip |
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Notes: |
application/zip |
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Label: |
8b - RS-760.zip |
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Notes: |
application/zip |
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Label: |
8c - RS-804.zip |
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Notes: |
application/zip |
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Label: |
9-10-11a - RS-758.zip |
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Notes: |
application/zip |